From Florence :

• highway A1
  Raccordo Siena Firenze ( Siena - Firenze motorway )
  Exit Colle Val D’Elsa North . After 50 meters turn to the left (Volterra )
  Within Colle Val d’Elsa , turn to the right to Volterra
  You are now on the road n. SS 68 for 25 km about
  Three km before Volterra , turn to the right to Pisa – Pontedera
  After 3-4 km turn to the right to Ulignano – Sensano
  You are now on a country road. Go straight on for about 4 km and you will see the yellow sign ‘ Villa di Scopicci' .
  Welcome!
  

From Pisa :

• highway A12 ( Genova – Pisa )
  Exit Pisa Centro ( Airport )
  Follow the motorway S.G.C. to Florence
  Exit Pontedera
  Follow the signs to Volterra
  ( Approximately 10 km from Volterra) , near restaurant Molino d’Era
  - At the cross road , turn to the left , direction Colle Val d’Elsa . After meter100 turn again to the right. follow this road for about 3 km.. At the cross road turn to your left (direction Ulignano Sensano). You are now on a country road. Go straight on for about 4 km and you will see the yellow sign ‘ Villa di Scopicci’.
  Welcome!